Roll-drawing and die-drawing of toughened poly(ethylene terephthalate). Part 2. Fracture behaviour

摘要

Orientation of polymers in the solid-state has been used for a long time in enhancing the properties of the products and the die-drawing process at Leeds University (UK) and the roll-drawing process at IMI (Canada) have been used to produce oriented polymer products in a wide variety of shape and sizes. In this work, we explore the fracture behaviour of isotropic and oriented toughened poly(ethylene terephthalate) (PET) in order to improve the toughness of the oriented products in a direction other than the principal draw direction. The fracture behaviour of isotropic and oriented PET homopolymer and the two PET blends (containing 10% polyethylene elastomer and 10% compatibilized elastomer) was studied using the multi-specimen J-integral approach. In the isotropic case, the compatibilized blend had higher toughness than the homopolymer and the non-compatibilized blend. The oriented sheets from the die-drawing and roll-drawing process, drawn to a draw ratio of 3.2 at 170 \ub0C were tested with the initial notch both parallel and perpendicular to the draw direction. For the former case, the compatibilized blend was tougher and in the other direction the drawn homopolymer was tougher than the blends. At similar draw ratios, the fracture behaviour and the toughness of the oriented sheets from the die-drawing and roll-drawing processes were identical.